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Präparation, Charakterisierung und optische Eigenschaften von Kupfer-Nano-Clustern in Plasmapolymermatrizen

Präparation, Charakterisierung und optische Eigenschaften von Kupfer-Nano-Clustern in Plasmapolymermatrizen

          
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About the Book

Inhaltsangabe: Einleitung: Die Plasmapolymerisation ist ein Verfahren zur Produktion von dünnen Polymerschichten bis zu 105 nm Dicke. Bei dem Plasmapolymerisationsprozess wird durch das Einwirken eines Plasmas auf gasförmige, organische Moleküle eine Polymerbeschichtung erzeugt. Die so gebildeten Polymerschichten weisen eine komplexe und hochvernetzte Struktur auf. In den letzten 20 Jahren hat die Plasmapolymerisation einen großen Aufschwung erfahren und sich zu einem Verfahren mit großer technischer Bedeutung entwickelt. Eingesetzt wird die Plasmapolymerisation zur Produktion von wasserundurchlässigen sowie wasserabweisenden Materialien. Weitere Einsatzgebiete finden sich im Korrosionsschutz, in der Herstellung von abriebsmindernden Schichten, Diffusionsbarrieren und elektrisch leitfähigen Schichten. Im Gegensatz zur Plasmapolymerisation werden Metallcluster schon seit Jahrhunderten genutzt. Die ersten Anwendungen finden sich bereits im Altertum in der Herstellung farbiger Gläser durch Einfärben mit Metallpartikeln. Auf ein großes wissenschaftliches Interesse stießen die Metallcluster bereits zu Anfang dieses Jahrhunderts. So beschrieb Wo. Ostwald besonders eindrucksvoll 1915 in dem Buch „Die Welt der vernachlässigten Dimensionen" Cluster und ihre Eigenschaften. Als Cluster werden in der Chemie und Festkörperphysik kleine Teilchen von Metallen und Halbmetallen bezeichnet. Es werden dabei kleine Cluster mit einem Durchmesser bis zu 4 nm von großen Clustern mit einer Größe von 4 bis 100 nm unterschieden. Die Atomanzahl reicht bei kleinen Clustern von weniger als 10 bis zu 500 Atomen. Die großen Cluster, welche auch Kolloide genannt werden, können bis zu 10 Atome beinhalten. Die Präparation von Clustern aus verschiedensten Metallen in Plasmapolymermatrizen wird in der Literatur ausführlich beschrieben. Ebenso wird von der Einbettung bimetallischer Cluster in Polymermatrizen berichtet. Besondere Aufmerksamkeit galt vor allem Gold- und Silberclustern, welche sich


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Product Details
  • ISBN-13: 9783838614496
  • Publisher: Diplom.de
  • Binding: Paperback
  • Language: German
  • Returnable: N
  • Spine Width: 6 mm
  • Width: 148 mm
  • ISBN-10: 3838614496
  • Publisher Date: 17 Apr 1999
  • Height: 210 mm
  • No of Pages: 96
  • Series Title: German
  • Weight: 136 gr


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