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Einfluss Von Grenzflachen Auf Die Fluidik Dunner Polymerfilme

Einfluss Von Grenzflachen Auf Die Fluidik Dunner Polymerfilme

          
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About the Book

Zahlreiche Technologien basieren heutzutage auf dunnen Filmen und deren Eigenschaften. Dies sind beispielsweise elektronische Bauteile, Beschichtungen wie Photolacke, die in der Lithographie Anwendung finden, oder mikrofluidische Messzellen, die eine breite Analyse kleinster Flussigkeitsmengen ermoglichen. In all diesen Bereichen ist die genaue Kenntnis von Fliesseigenschaften auf der Nanometerskala unverzichtbar. Ziel der hier vorliegenden Arbeit ist, die relevanten Parameter zu charakterisieren und zu quantifizieren, die das Fliessverhalten dunner Filme beeinflussen. In einem ersten Teil der Arbeit wurde der Prozess der spinodalen Entnetzung genauer untersucht. Beim quantitativen Vergleich eines Experiments mit der theoretischen Erwartung stellte sich heraus, dass thermisches Rauschen im Filmvolumen die Entnetzungsdynamik signifikant beeinflusst. Neben einer Anderung der Zeitskala verursachen thermische Fluktuationen eine Vergroberung der Strukturen, die sich an der freien Filmoberflache bilden; das Kapillarwellenspektrum verschiebt sich. Im zweiten Teil dieser Arbeit wurden Entnetzungsfronten einzelner Locher in Polymerfilmen untersucht. Hier lag der Schwerpunkt auf der Randbedingung an die Stromung an der Grenzflache zum festen Substrat, charakterisiert durch die Sliplange. Im Verlauf der Arbeit konnten zwei Methoden entwickelt werden, die eine Quantifizierung der Sliplange erlauben. Ein erster Ansatz geht hierbei von der Entnetzungsgeschwindigkeit aus. Aus dem genauen Verlauf des Lochwachstums konnte die Sliplange grob abgeschatzt werden. Als bessere Methode erwies sich jedoch die Analyse von Randwulsten, die sich um jedes Loch ausbilden. Auf der Grundlage eines neuen Lubrikationsmodells fur starkes Rutschen konnte ein Auswertungsverfahren entwickelt werden, das die Bestimmung sowohl der Sliplange als auch der Filmviskositat aus dem Randwulstprofil ermoglicht. Diese neue, konsistente Methode zur Quantifizierung der Randbedingung an der Grenzflache zum Substrat bietet die Grundlage zur Untersuchung weiterer Systeme und dient somit der Optimierung technologischer Anwendungen dunner Filme.


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Product Details
  • ISBN-13: 9783832513542
  • Publisher: Logos Verlag Berlin
  • Binding: Paperback
  • Language: German
  • Returnable: N
  • Spine Width: 0 mm
  • Width: 145 mm
  • ISBN-10: 383251354X
  • Publisher Date: 30 Sep 2006
  • Height: 210 mm
  • No of Pages: 204
  • Series Title: German
  • Weight: 700 gr

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