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Desarrollo de sensores electroquímicos basados en furoiltioureas

Desarrollo de sensores electroquímicos basados en furoiltioureas

          
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About the Book

En la siguiente Memoria se hace un estudio de la naturaleza de los complejos que se forman entre un conjunto de 1-furoiltioureas y las sales CdCl2 y HgCl2, para evaluar y correlacionar sus propiedades con el comportamiento de los ligandos como ionóforos o modificantes en sensores electroquímicos potenciométricos y amperométricos. Se aborda primeramente el estudio de los ligandos, en particular mediante métodos espectroscópicos de absorción tales como FTIR y Raman, para identificar aquellas vibraciones que pueden servir como indicadores del proceso de interacción entre el ligando y el metal, y luego se estudian estas interacciones en los complejos entre los ligandos y las sales metálicas. Se investiga la determinación de Cd(II) mediante Voltamperometría de Impulso Diferencial con el método de Redisolución Anódica sobre los electrodos de pasta de carbono modificados con aquellos compuestos que mostraron mejor comportamiento preliminar. También se realizan experimentos encaminados a establecer las condiciones electroquímicas e instrumentales óptimas del método. En todos los estudios se ha correlacionado la respuesta analítica con los cambios observados en los espectros FTIR y Raman.


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Product Details
  • ISBN-13: 9783846569290
  • Publisher: Eae Editorial Academia Espanola
  • Publisher Imprint: Eae Editorial Academia Espanola
  • Height: 229 mm
  • No of Pages: 312
  • Series Title: Spanish
  • Weight: 459 gr
  • ISBN-10: 3846569291
  • Publisher Date: 03 Nov 2011
  • Binding: Paperback
  • Language: Spanish
  • Returnable: N
  • Spine Width: 18 mm
  • Width: 152 mm


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