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Contributions Théoriques À l'Étude Des Polymères Aux Interfaces

Contributions Théoriques À l'Étude Des Polymères Aux Interfaces

          
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About the Book

Cette thèse s'inscrit dans le cadre général de l'étude des propriétés statistiques de chaînes polymères aux interfaces. Il s'agit d'un travail théorique qui a pour but de relier les propriétés macroscopiques de l'interface à l'organisation microscopique des chaînes. La couche de polymères est décrite en termes de boucles et de queues formées par les polymères adsorbés. Cette théorie est appliquée au problème de la tension de surface de liquides polymères. La comparaison de ces résultats théoriques avec des mesures expérimentales de tension de surface, met en lumière le rôle de la tensio-activité des bouts de chaînes et celui de l'entropie associée à la distribution des boucles. Cette théorie est ensuite étendue au cas de l'adsorption de polyélectrolytes sur une surface de charge opposée. Enfin, sont abordées la question de l'influence de la géométrie concave sur la structure d'une brosse de polymères et l'étude des connecteurs polymères mobiles. Les propriétés adhésives des jonctions formées par ces derniers dépendent alors fortement de la géométrie des objets connectés et des caractéristiques des polymères.


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Product Details
  • ISBN-13: 9786131512148
  • Publisher: Omniscriptum
  • Publisher Imprint: Omniscriptum
  • Height: 229 mm
  • No of Pages: 256
  • Series Title: Omn.Univ.Europ.
  • Weight: 381 gr
  • ISBN-10: 6131512140
  • Publisher Date: 28 Feb 2018
  • Binding: Paperback
  • Language: French
  • Returnable: N
  • Spine Width: 15 mm
  • Width: 152 mm


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